QUICK FACTS
Created Jan 0001
Status Verified Sarcastic
Type Existential Dread
metamorphic rocks, metamorphism, metasomatism, hydrothermal fluids, calcium, magnesium, iron, manganese, aluminium, silicate minerals

Skarn

“Skarns, or tactites as they are sometimes called, are a fascinating class of coarse-grained metamorphic rocks. They don't just form from existing rocks being...”

Contents
  • 1. Overview
  • 2. Etymology
  • 3. Cultural Impact

Skarns, or tactites as they are sometimes called, are a fascinating class of coarse-grained metamorphic rocks . They don’t just form from existing rocks being squeezed and heated; oh no, that would be too simple. Skarns are born from a more complex dance of metamorphism and metasomatism , specifically when hydrothermal fluids decide to have a rather aggressive conversation with carbonate-bearing rocks. This can happen during regional or contact metamorphism, which, if you’re keeping score, means high temperatures are involved. It’s not just about recrystallization; it’s about chemical alteration, a wholesale replacement. Think of it as a geological makeover, but with a lot more heat and pressure, and significantly less flattering lighting.

These rocks are typically rich in minerals that are, let’s say, rather fond of calcium , magnesium , iron , manganese , and aluminium , all bound together by silicate minerals . These are the so-called calc-silicate minerals , and they are the signature of a skarn. They don’t just pop into existence; they form as a direct result of these hydrothermal fluids aggressively interacting with a protolith —the original rock. This protolith can be anything from an igneous rock to a sedimentary rock . However, skarns have a particular fondness for hanging out near granitic plutons , often congregating around faults or shear zones . They have a penchant for intruding into layers of carbonate rocks , like dolomite or limestone .

The hydrothermal fluids responsible for this dramatic transformation can originate from a surprisingly diverse set of sources. We’re talking about magmatic fluids, of course, but also metamorphic, meteoric , or marine waters, or even a cocktail of these. The final mineral composition of a skarn is a direct reflection of this complex interplay between the fluid’s chemistry and the original rock’s composition. It’s a geological fingerprint, if you will.

Now, if these skarns happen to contain a significant amount of ore mineralization—enough to make mining it profitable, that is—they get a promotion. They are then classified as a skarn deposit. Because, naturally, if something is valuable, it deserves its own special classification.

Etymology

The word “skarn” itself is a rather old term, originating from Swedish mining. It was initially used to describe a specific type of silicate gangue , or what miners would consider waste rock, that was found alongside iron-ore bearing sulfide deposits. These particular skarns were observed to be replacing Palaeoproterozoic age limestones in the Persberg mining district of Sweden. It’s a name that carries the weight of history, of generations of miners sifting through rock, trying to find the good stuff.

Petrology

As I’ve hinted, skarns are fundamentally composed of calcium-iron-magnesium-manganese-aluminum silicate minerals. But beyond their mineralogical composition, they are also economically significant. Skarn deposits are prized as sources for a whole host of metals, including tin , tungsten , manganese , copper , gold , zinc , lead , nickel , molybdenum , and iron . They are, in essence, geological treasure chests.

The formation of a skarn is a prime example of metasomatic processes occurring during metamorphism, typically at the interface between two distinct lithologic units. While skarns can technically form in almost any rock type—shale , granite , or basalt are not entirely immune—they are most commonly found in carbonate rocks like limestone or dolomite. Their preferred locations are near plutons, along faults and major shear zones, within shallow geothermal systems, and even on the ocean floor. The specific mineralogy of any given skarn is, predictably, heavily influenced by the mineralogy of its original protolith.

The characteristic mineralogy of skarns is dominated by garnet and pyroxene . Alongside these major players, you’ll find a diverse array of associated calc-silicate minerals, such as idocrase , wollastonite , actinolite , magnetite or hematite , epidote , and scapolite . Because skarns are the product of silica-rich aqueous fluids brimming with incompatible elements , they often host a surprising variety of uncommon mineral types. Keep an eye out for tourmaline , topaz , beryl , corundum , fluorite , apatite , barite , strontianite , tantalite , anglesite , and others. It’s a veritable mineralogical cabinet of curiosities.

Classification

Skarns can be categorized in several ways, depending on what geological feature you’re focusing on. One common method is to classify them based on their protolith . If the original rock was of sedimentary origin, the resulting skarn is termed an exoskarn. If the protolith was igneous, it’s an endoskarn.

Further refinement comes from examining the dominant composition and the resulting alteration assemblages, again looking at the protolith. Skarns containing minerals like olivine , serpentine , phlogopite , magnesium clinopyroxene , orthopyroxene , spinel , pargasite , and minerals from the humite group are characteristic of a dolomitic protolith and are classified as magnesian skarns. The contrasting category, calcic skarns, are derived from a limestone protolith and are characterized by dominant mineral assemblages featuring garnet , clinopyroxene, and wollastonite .

There’s also a term for rocks that share some characteristics with skarns but are finer-grained, lack iron, and still possess a skarn-like appearance. These are called “skarnoids.” They are essentially an intermediate stage, bridging the gap between a fine-grained hornfels and a coarse-grained skarn.

Skarn Ore Deposits

When skarn rocks serve as the gangue —the host rock for valuable minerals—in metal ore deposits, these deposits are known as skarn deposits. They can form through various combinations of closed metamorphism or open-system metasomatism, though the prevailing theory is that most skarn deposits are linked to magmatic-hydrothermal systems. These deposits are typically classified by their dominant economic element; for instance, a copper (Cu) skarn deposit or a molybdenum (Mo) skarn deposit.

Fe (Cu, Ag, Au) Skarn Deposits

The typical tectonic setting for calcic Fe skarns is within oceanic island arcs . The host rocks here often range from gabbro to syenite , frequently found in association with intruding limestone layers. Magnesium Fe skarns, on the other hand, tend to form in continental margin settings. Their host rocks are more commonly granodiorite to granite , and they are associated with intruding dolomite and other dolomitic sedimentary rocks. The primary ore in these types of skarn deposits is magnetite , often grading between 40 to 60 percent. Chalcopyrite , bornite , and pyrite are usually present as minor ore components.

Cu (Au, Ag, Mo, W) Skarn Deposits

For copper deposits, the common tectonic setting involves Andean-type plutons intruding older continental-margin carbonate layers. The host rocks are typically quartz diorite and granodiorite . In these deposits, pyrite, chalcopyrite, and magnetite are generally found in higher abundances.

Formation

Broadly speaking, there are two principal types of skarns that form: exoskarns and endoskarns, as mentioned earlier.

Exoskarns are the more prevalent type. They develop on the exterior of an intrusive igneous body where it comes into contact with a reactive rock unit. This occurs when fluids, residual from the intrusion’s crystallization, are expelled from the cooling magma mass, often during a process known as boiling. When these fluids encounter reactive rocks, particularly carbonates like limestone or dolomite, they initiate a chemical alteration process, a form of infiltration metasomatism .

Endoskarns, conversely, form within the intrusive body itself. This happens in areas that have become fractured, perhaps due to cooling joints or the development of stockworks , creating permeable zones. Fluids originating from the intrusion, after potentially interacting with surrounding rocks (the protolith ), can then alter these permeable areas. Consequently, the composition and textures of the original protoliths play a crucial role in shaping the resulting endoskarn. These are considered relatively rare occurrences.

Reaction skarns are a bit different; they form through isochemical metamorphism. This means the overall chemical composition remains largely the same, but the minerals recrystallize. This typically occurs in thinly interlayered sedimentary units, involving small-scale metasomatic exchange between adjacent layers.

Skarnoids, as described before, are fine-grained, iron-poor calc-silicate rocks. They are often found situated between hornfels and coarser-grained skarns, acting as a transitional zone. Skarnoids tend to closely mirror the composition of their protolith.

Most large skarn deposits exhibit a progression from early metamorphic stages—which yield hornfels , reaction skarns, and skarnoids—to later metamorphic stages, producing coarser-grained, ore-bearing skarns. The initial magma intrusion triggers contact metamorphism in the surrounding rocks, leading to the formation of hornfels. The recrystallization and phase changes within the hornfels are indicative of the original protolith’s composition. Following the hornfels stage, metasomatism takes place, driven by hydrothermal fluids from various sources—magmatic, metamorphic, marine, meteoric, or a combination. This process, sometimes referred to as isochemical metamorphism, can generate a wide spectrum of calc-silicate minerals, particularly in impure lithological units and along fluid boundaries where minor metasomatism occurs. This can happen in rocks like argillite , limestone , and banded iron formation .

The skarn deposits that are economically significant for their metal content are generally the result of large-scale metasomatism. In these cases, the composition of the fluid is the dominant factor controlling the skarn and its associated ore mineralogy. These economically important skarns are typically coarser-grained and do not strongly reflect the composition of the protolith or the surrounding country rocks.

Less common types of skarns can form when the hydrothermal fluids interact with sulfidic or carbonaceous rocks, such as black shales, graphite shales, banded iron formations, and occasionally even salt or evaporites . In these scenarios, the fluid reaction is less about simple ion exchange and more influenced by the redox-oxidation potential of the wall rocks.

Ore Deposits

The primary economic metals recovered from skarn deposits are copper , tungsten , iron , tin , molybdenum , zinc -lead , and gold . Other metals of secondary economic importance include uranium , silver , boron , fluorine , and rare-earth elements .

Some notable examples of major economic skarn deposits, both historically important and currently active, include:

  • Iron skarns: The Dashkesan Mine in Azerbaijan is a prime example.
  • Copper skarns: The Bingham Canyon Mine in Utah, USA, is a world-renowned copper skarn deposit.
  • Tungsten skarns: The Sangdong mine in South Korea is a significant tungsten skarn deposit.
  • Gold-bearing skarns: The Hedley Mascot Mine in British Columbia, Canada, is a famous gold-bearing skarn.
  • Zinc-lead skarns: The deposits at Santa Eulalia, Chihuahua , Mexico, are significant examples of zinc-lead skarns.
  • Nickel skarns: The Avebury Mine in Zeehan, Tasmania (Australia), is an example of a nickel skarn deposit.
  • Molybdenum skarns: The Yangchiachangtze mine in China is noted for its molybdenum skarn deposits.

See also

  • Ore genesis – The processes by which various types of mineral deposits form within the Earth’s crust.

Wikimedia Commons hosts a variety of media related to skarns.

Notes

  • ^ The scale referred to here is on the order of a few centimeters.

References

  • ^ a b Einaudi, M. T.; Meinert, L. D.; Newberry, R. J. (1981), “Skarn Deposits”, Seventy-Fifth Anniversary Volume, Society of Economic Geologists, doi :10.5382/av75.11, ISBN 978-1-9349-6953-3, retrieved 2023-07-14
  • ^ a b c d e Einaudi, Marco T.; Burt, Donald M. (1982). “Introduction; terminology, classification, and composition of skarn deposits”. Economic Geology. 77 (4): 745–754. Bibcode :1982EcGeo..77..745E. doi :10.2113/gsecongeo.77.4.745.
  • ^ a b c d e f g h i j Ray, G.E., and Webster, I.C.L. (1991): An Overview of Skarn Deposits; in Ore Deposits, Tectonics and Metallogeny in the Canadian Cordillera; McMillan, W.J., compiler, B. C. Ministry of Energy, Mines and Petroleum Resources, Paper 1991-4, pages 213-252.
  • ^ a b c d e f g h i j k l m n o p Meinert, L.D., 1992. Skarns and Skarn Deposits; Geoscience Canada, Vol. 19, No. 4, p. 145-162.
  • ^ a b c d e Hammarstrom, J.M., Kotlyar, B.B., Theodore, T.G., Elliott, J.E., John, D.A., Doebrich, J.L., Nash, J.T., Carlson, R.R., Lee, G.K., Livo, K.E., Klein, D.P., 1995. Cu, Au, and Zn-Pb Skarn Deposits, Chapter 12; United States Geological Survey: Preliminary Compilation of Descriptive Geoenvironmental Mineral Deposit Models: https://pubs.usgs.gov/of/1995/ofr-95-0831/CHAP12.pdf .
  • ^ a b Burt, Donald M. (1977). “Mineralogy and petrology of skarn deposits” (PDF). Societa Italiana Mineralogia Petrolgia Rendiconti. 33 (2): 859–873.
  • ^ a b Jolis, E. M.; Troll, V. R.; Harris, C.; Freda, C.; Gaeta, M.; Orsi, G.; Siebe, C. (2015-11-15). “Skarn xenolith record crustal CO2 liberation during Pompeii and Pollena eruptions, Vesuvius volcanic system, central Italy”. Chemical Geology. 415: 17–36. Bibcode :2015ChGeo.415…17J. doi :10.1016/j.chemgeo.2015.09.003. ISSN 0009-2541.
  • ^ a b “Hydrothermal and Skarn Deposits”. www.geol-amu.org . Retrieved 2018-03-29.
  • ^ a b Nadoll, Patrick; Mauk, Jeffrey L.; Leveille, Richard A.; Koenig, Alan E. (2015-04-01). “Geochemistry of magnetite from porphyry Cu and skarn deposits in the southwestern United States”. Mineralium Deposita. 50 (4): 493–515. Bibcode :2015MinDe..50..493N. doi :10.1007/s00126-014-0539-y. ISSN 0026-4598. S2CID 128816207.
  • ^ a b Soloviev, Serguei G.; Kryazhev, Sergey (2017). “Geology, mineralization, and fluid inclusion characteristics of the Chorukh-Dairon W–Mo–Cu skarn deposit in the Middle Tien Shan, Northern Tajikistan”. Ore Geology Reviews. 80: 79–102. Bibcode :2017OGRv…80…79S. doi :10.1016/j.oregeorev.2016.06.021.
  • ^ Whitley, Sean; Halama, Ralf; Gertisser, Ralf; Preece, Katie; Deegan, Frances M.; Troll, Valentin R. (2020-10-18). “Magmatic and Metasomatic Effects of Magma–Carbonate Interaction Recorded in Calc-silicate Xenoliths from Merapi Volcano (Indonesia)”. Journal of Petrology. 61 (4). doi :10.1093/petrology/egaa048. ISSN 0022-3530.
  • ^ Zarayskiy, G. P.; Zharikov, V. A.; Stoyanovskaya, F. M.; Balashov, V. N. (1987). “The experimental study of bimetasomatic skarn formation”. International Geology Review. 29 (6) (published 29 June 2010): 761–858. Bibcode :1987IGRv…29..629Z. doi :10.1080/00206818709466179.
  • ^ Korzhinskii, D.S. (1948). “Petrology of the Tur’insk skarn deposits of copper”. 68 (10). Ser. Rundnykh Mestorozhdenii. Academy nauk SSSR: Institute of Geology Nauk Trudy: 147. {{cite journal }} : Cite journal requires |journal= (help)
  • ^ a b Zharikov, V. A. (1970). “Skarns (Part I)”. International Geology Review. 12 (5) (published 7 September 2009): 541–559. Bibcode :1970IGRv…12..541Z. doi :10.1080/00206817009475262.
  • ^ a b Zharikov, V. A. (1970). “Skarns (Part II)”. International Geology Review. 12 (6) (published 7 September 2009): 619–647, 760–775. Bibcode :1970IGRv…12..619Z. doi :10.1080/00206817009475270.

External links

Look up skarn or tactite in Wiktionary, the free dictionary.

Types of rocks Igneous rock Sedimentary rock Metamorphic rock Specific varieties